Facile C-H bond activation on a transient gallium imide.
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DOI: 10.1039/d2cc01857h
Abstract: Reaction of NacNacGa with azide N3SiMe3 results in the generation of a transient imide NacNacGa(NSiMe3) that can cleave unactivated sp3 C-H and sp2 C-H bonds of different substrates, affording gallium amides. Pyridine, cyclohexanone, ethyl acetate,… read more here.
Keywords: activation transient; gallium; bond activation; facile bond ... See more keywords
Facile C-N bond cleavage of primary aliphatic amines by (salen)ruthenium(VI) nitrido complexes.
Sign Up to like & getrecommendations! Published in 2022 at "Dalton transactions"
DOI: 10.1039/d2dt00600f
Abstract: We report the first example of oxidative cleavage of the strong C-N bonds of primary amines by a ruthenium(VI) nitrido complex. The driving force for this very fast C-N cleavage reaction comes from the formation… read more here.
Keywords: cleavage; bond cleavage; ruthenium nitrido; facile bond ... See more keywords