Occurrence of slow relaxation of the magnetization in a family of copper(II)/manganese(II) quasi-isotropic complexes with different ground spin states.
Sign Up to like & getrecommendations! Published in 2022 at "Dalton transactions"
DOI: 10.1039/d2dt02807g
Abstract: A family of copper(II)/manganese(II) new clusters with the formulas [CuIINaI(L2)(MeOH)(ClO4)] (1), [CuII2MnII(S,S-L3)2(MeOH)](ClO4)2 (2SS), [{CuIIMnII(L1)(H2O)2(MeOH)}{CuII(L1)}2](ClO4)2 (3), [(μ1,3-N3)2{CuIIMnII(L2)(H2O)}2{CuII(L2)2](ClO4)}2 (4) and [(μ1,1-N3)2{CuIIMnII(L1)(N3)}2{CuIINaI(L1)(MeOH)}2](ClO4)2 (5) with L1 = N,N'-ethylene-bis(3-methoxysalicylaldiimine), L2 = N,N'-ethylene-bis(3-ethoxysalicylaldiimine) and L3 = N,N'-cyclohexane-bis(3-ethoxysalicylaldiimine), has been synthesized, and… read more here.
Keywords: clo4; family copper; quasi isotropic; copper manganese ... See more keywords
[Cu2(en)2(N3)4]n – A new member in the family of copper(II)-azido assemblies: structural and magnetic studies
Sign Up to like & getrecommendations! Published in 2017 at "Journal of Coordination Chemistry"
DOI: 10.1080/00958972.2017.1290798
Abstract: Abstract A copper(II) complex with ethylene diamine and azide, viz., [Cu2(en)2(N3)4]n has been isolated under self-assembling conditions and characterized both structurally and magnetically in order to probe the role of reactant molar ratios in generating… read more here.
Keywords: azido assemblies; member family; copper; copper azido ... See more keywords
Adding to the Family of Copper Complexes Featuring Borohydride Ligands Based on 2-Mercaptopyridyl Units
Sign Up to like & getrecommendations! Published in 2019 at "Inorganics"
DOI: 10.3390/inorganics7080093
Abstract: Borohydride ligands featuring multiple pendant donor functionalities have been prevalent in the chemical literature for many decades now. More recent times has seen their development into new families of so-called soft scorpionates, for example, those… read more here.
Keywords: family copper; copper complexes; adding family; borohydride ligands ... See more keywords