Pentadecanuclear Fe-Containing Polyoxometalate Catalyst for Visible-Light-Driven Generation of Hydrogen.
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DOI: 10.1021/acs.inorgchem.1c00267
Abstract: The structurally new, carbon-free pentadecanuclear Fe-containing polyoxometalate, Na21[NaFe15(OH)12(PO4)4(A-α-SiW9O34)4]·85H2O (Na21-Fe15P4(SiW9)4), was synthesized using a facile one-pot, solution-based synthetic approach and systematically characterized by various spectroscopic techniques. Single-crystal X-ray diffraction reveals that the title complex is composed… read more here.
Keywords: hydrogen; fe15p4 siw9; polyoxometalate catalyst; containing polyoxometalate ... See more keywords