[Fe2(μ-S2)(CN)2(CO)4]2-, [Fe2(μ-SH)2(CN)2(CO)4]2-, and [Fe2(μ-SH)(μ-SCH2NH2)(CN)2(CO)4]2- Related to the Biosynthesis of the [2Fe]H Site of the [FeFe]Hydrogenases.
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DOI: 10.1021/acs.inorgchem.5c03496
Abstract: This paper discusses diiron complexes implicated as intermediates in the biosynthesis of the [2Fe]H site of the [FeFe]-hydrogenases. These complexes include [Fe2(μ-SH)(μ-SR)(CN)2(CO)4]2- (R = H, CH2NH2 [2H,R]2-), which are available from the new precursor [Fe2(μ-S2)(CN)2(CO)4]2-… read more here.
Keywords: fe2; fe2 fe2; fefe hydrogenases; 2fe site ... See more keywords