Functional Nonheme Diiron(II) Complexes Catalyze the Direct Reduction of Nitrite to Nitric Oxide in Relevance to the Diiron Protein YtfE.
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DOI: 10.1021/acs.inorgchem.5c00753
Abstract: The present work reports the functional modeling chemistry of YtfE, which features a nonheme diiron active site and mediates the direct reduction of NO2- to NO. The model complex, [Fe2(HPTP)Cl2]1+ (1), reduces NO2- to NO… read more here.
Keywords: fe2 hptp; chemistry; hptp; reduction ... See more keywords