2-(Diphenylphosphino)benzaldehyde or isopropyldiphenylphosphine substituted diiron dithiolate complexes
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DOI: 10.1016/j.poly.2017.08.029
Abstract: Abstract Reaction of (μ-SCH2CH2CH2S-μ)Fe2(CO)6 (1) with 2-(diphenylphosphino)benzaldehyde in the presence of Me3NO·2H2O yielded monosubstituted complex (μ-SCH2CH2CH2S-μ)Fe2(CO)5[Ph2P(2-C6H4CHO)] (3) and disubstituted complex (μ-SCH2CH2CH2S-μ)Fe2(CO)4[Ph2P(2-C6H4CHO)]2 (4) in 47% and 23% yields, respectively, whereas reaction of [μ-SCH2CH(CH3)S-μ]Fe2(CO)6 (2) with 2-(diphenylphosphino)benzaldehyde… read more here.
Keywords: me3no 2h2o; fe2 ph2p; ch3; fe2 ... See more keywords