Single-Step Access to Thiolate-Supported, Six-Iron Clusters with an Authentic Carbide: Synthesis of [Fe6(μ6-C)(μ2-Stol)(μ2-CO)2(CO)12]3 via Non-PSEPT, Redox Intermediates.
Sign Up to like & getrecommendations! Published in 2025 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.4c05362
Abstract: We report a general synthetic method to access iron-carbide(carbonyl) clusters ligated by thiolate. We previously established that multiple neutral ligand substitution (phosphine) was enabled by utilizing the conventional six-iron carbide cluster [Fe6(μ6-C)(μ2-CO)4(CO)12]2- and generating the… read more here.
Keywords: thiolate; iron; six iron; fe6 ... See more keywords
The mechanism of Mo-nitrogenase: from N2 capture to first release of NH3.
Sign Up to like & getrecommendations! Published in 2024 at "Dalton transactions"
DOI: 10.1039/d4dt02606c
Abstract: Mo-nitrogenase hydrogenates N2 to NH3. This report continues from the previous paper [I. Dance, Dalton Trans., 2024, 53, 14193-14211] that described how the active site FeMo-co of the enzyme is uniquely able to capture and… read more here.
Keywords: reaction; nh3; nitrogenase; step ... See more keywords