Curved Nanographene Featuring Two sp3 Stereocenters via Oxidative Cyclodehydrogenation with Aryl Rearrangement.
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DOI: 10.1021/acs.orglett.5c03555
Abstract: Curved nanographene 1, featuring two sp3 stereocenters, was synthesized through a Scholl-type oxidative cyclodehydrogenation accompanied by an unexpected aryl rearrangement. Single-crystal X-ray diffraction revealed that two sp3 carbons in the fused polycyclic skeleton induce pronounced… read more here.
Keywords: nanographene featuring; curved nanographene; featuring two; sp3 stereocenters ... See more keywords
A mono-metallic Pd(ii)-cage featuring two different polar binding sites.
Sign Up to like & getrecommendations! Published in 2019 at "Chemical communications"
DOI: 10.1039/c8cc09195a
Abstract: The tetra-α isomer of a super aryl-extended tetra-pyridyl calix[4]pyrrole self-assembles into a mono-metallic Pd(ii)-cage featuring two different and converging polar binding sites. Mono- and di-topic polar guests are bound reversibly in the cage. A mechanism… read more here.
Keywords: featuring two; metallic cage; cage featuring; mono metallic ... See more keywords