Synthesis and characterization of trigonal bipyramidal FeIII complexes and their solution behavior.
Sign Up to like & getrecommendations! Published in 2021 at "Polyhedron"
DOI: 10.1016/j.poly.2021.115384
Abstract: A series of air-stable trigonal bipyramidal FeIII complexes supported by a redox non-innocent NNN pincer ligand, Cz tBu(PyrR)2 - (R = iPr, Me, or H), were synthesized, fully characterized, and utilized for the investigation of… read more here.
Keywords: feiii; bipyramidal feiii; trigonal bipyramidal; feiii complexes ... See more keywords
Enhancing Stability of Tannic Acid-FeIII Nanofiltration Membrane for Water Treatment: Intercoordination by Metal-Organic Framework.
Sign Up to like & getrecommendations! Published in 2022 at "Environmental science & technology"
DOI: 10.1021/acs.est.2c05048
Abstract: Tannic acid (TA)-FeIII nanofiltration (NF) membrane has been demonstrated to possess more favorable removal of trace organic contaminants (TrOCs) over the conventional polyamide NF membrane. However, the drawback of acid instability severely hinders the practical… read more here.
Keywords: feiii; water; acid; membrane ... See more keywords
Determining the Inherent Selectivity for Carbon Radical Hydroxylation versus Halogenation with FeIII(OH)(X) Complexes: Relevance to the Rebound Step in Non-heme Iron Halogenases.
Sign Up to like & getrecommendations! Published in 2020 at "Journal of the American Chemical Society"
DOI: 10.1021/jacs.0c00493
Abstract: The first structural models of the proposed cis-FeIII(OH)(halide) intermediate in the non-heme iron halogenases were synthesized and examined for their inherent reactivity with tertiary carbon radicals. Selective hydroxylation occurs for these cis-FeIII(OH)(X) (X = Cl,… read more here.
Keywords: carbon; feiii; heme iron; feiii complexes ... See more keywords
Generating Potent C-H PCET Donors: Ligand-Induced Fe-to-Ring Proton Migration from a Cp*FeIII-H Complex Demonstrates a Promising Strategy.
Sign Up to like & getrecommendations! Published in 2020 at "Journal of the American Chemical Society"
DOI: 10.1021/jacs.0c09363
Abstract: Highly reactive organometallic species that mediate reductive proton-coupled electron transfer (PCET) reactions are an exciting area for development in catalysis, where a key objective focuses on tuning the reactivity of such species. This work pursues… read more here.
Keywords: feiii; proton; ligand induced; feiii dppe ... See more keywords
Regulating the Spin State of FeIII Enhances the Magnetic Effect of the Molecular Catalysis Mechanism.
Sign Up to like & getrecommendations! Published in 2022 at "Journal of the American Chemical Society"
DOI: 10.1021/jacs.2c01153
Abstract: Aqueous-phase oxygen evolution reaction (OER) is the bottleneck of water splitting. The formation of the O-O bond involves the generation of paramagnetic oxygen molecules from the diamagnetic hydroxides. The spin configurations might play an important… read more here.
Keywords: effect; feiii; molecular catalysis; mechanism ... See more keywords
Mixed-valence {FeII2FeIII4} hexanuclear complexes with thermally induced Fe(III) spin-crossover behavior.
Sign Up to like & getrecommendations! Published in 2022 at "Dalton transactions"
DOI: 10.1039/d2dt02041f
Abstract: Cyano-bridged mixed-valence {Fe6} hexanuclear complexes {[Tp4-MeFeII(CN)3]2[FeIII(Tpa)]2[FeIII(OR)(Tpa)]2}·6ClO4·S (Tp4-Me = tri(4-methyl-pyrazol-1-yl)borate, Tpa = tris(2-pyridylmethyl)amine; R = -CH3, S = 8MeOH 1, R = -C2H5, S = 6EtOH 2) have been obtained by building the units of [Tp4-MeFe(CN)3]-… read more here.
Keywords: feiii tpa; feiii; mixed valence; spin crossover ... See more keywords
Comprehension of the Route for the Synthesis of Co/Fe LDHs via the Method of Coprecipitation with Varying pH
Sign Up to like & getrecommendations! Published in 2022 at "Nanomaterials"
DOI: 10.3390/nano12091570
Abstract: Co/Fe-based layered double hydroxides (LDHs) are among the most promising materials for electrochemical applications, particularly in the development of energy storage devices, such as electrochemical capacitors. They have also been demonstrated to function as energy… read more here.
Keywords: feiii; coprecipitation; route synthesis; ldhs ... See more keywords