Synthesis and characterization of trigonal bipyramidal FeIII complexes and their solution behavior.
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DOI: 10.1016/j.poly.2021.115384
Abstract: A series of air-stable trigonal bipyramidal FeIII complexes supported by a redox non-innocent NNN pincer ligand, Cz tBu(PyrR)2 - (R = iPr, Me, or H), were synthesized, fully characterized, and utilized for the investigation of… read more here.
Keywords: feiii; bipyramidal feiii; trigonal bipyramidal; feiii complexes ... See more keywords
Determining the Inherent Selectivity for Carbon Radical Hydroxylation versus Halogenation with FeIII(OH)(X) Complexes: Relevance to the Rebound Step in Non-heme Iron Halogenases.
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DOI: 10.1021/jacs.0c00493
Abstract: The first structural models of the proposed cis-FeIII(OH)(halide) intermediate in the non-heme iron halogenases were synthesized and examined for their inherent reactivity with tertiary carbon radicals. Selective hydroxylation occurs for these cis-FeIII(OH)(X) (X = Cl,… read more here.
Keywords: carbon; feiii; heme iron; feiii complexes ... See more keywords