Iron(III)-Oxo Cluster Chemistry with Dimethylarsinate Ligands: Structures, Magnetic Properties, and Computational Studies.
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DOI: 10.1021/acs.inorgchem.0c02554
Abstract: A program has been initiated to develop FeIII/oxo cluster chemistry with the "pseudocarboxylate" ligand dimethylarsinate (Me2AsO2-) for comparison with the well investigated FeIII/oxo/carboxylate cluster area. The synthesis and characterization of three polynuclear FeIII complexes are reported, [Fe12O4(O2CtBu)8(O2AsMe2)17(H2O)3]Cl3 (1), Na2[Fe12Na2O4(O2AsMe2)20(NO3)6(Me2AsO2H)2(H2O)4](NO3)6… read more here.
Keywords: chemistry; feiii oxo; cluster; cluster chemistry ... See more keywords