Mixed-valence {FeII2FeIII4} hexanuclear complexes with thermally induced Fe(III) spin-crossover behavior.
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DOI: 10.1039/d2dt02041f
Abstract: Cyano-bridged mixed-valence {Fe6} hexanuclear complexes {[Tp4-MeFeII(CN)3]2[FeIII(Tpa)]2[FeIII(OR)(Tpa)]2}·6ClO4·S (Tp4-Me = tri(4-methyl-pyrazol-1-yl)borate, Tpa = tris(2-pyridylmethyl)amine; R = -CH3, S = 8MeOH 1, R = -C2H5, S = 6EtOH 2) have been obtained by building the units of [Tp4-MeFe(CN)3]-… read more here.
Keywords: feiii tpa; feiii; mixed valence; spin crossover ... See more keywords