Mono- and dinuclear tetraphosphabutadiene ferrate anions.
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DOI: 10.1039/c7dt04641c
Abstract: Reduction of [CpArFe(μ-Br)]2 (1, CpAr = C5(C6H4-4-Et)5) by potassium napthalenide, followed by the addition of white phosphorus, affords [K(18-c-6){CpArFe(η4-P4)}] (2, 18-c-6 = [18]crown-6), which features a planar cyclo-P42- ligand. The related diiron complex [Na2(THF)5(CpArFe)2(μ,η4:4-P4)] (3)… read more here.
Keywords: mono dinuclear; dinuclear tetraphosphabutadiene; tetraphosphabutadiene ferrate; ferrate anions ... See more keywords