Kinetically controlled asymmetric synthesis of silicon-stereogenic methoxy silanes using a planar chiral ferrocene backbone.
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DOI: 10.1039/c9cc03619a
Abstract: We present a mechanistic proposal for the desymmetrisation of dimethoxy silanes with alkyllithiums. The stereochemical pathway is highly defined by the coordination of the metal lithium, which suppresses the reversible interconversion of the various pentavalent… read more here.
Keywords: using planar; chiral ferrocene; planar chiral; ferrocene backbone ... See more keywords