Structures of 1,1′,3,3′-tetra(2-methyl-2-nonyl)ferrocenium(1+) salts of CB11H12−, B12F122−, BF4−, PF6−, and ClO3−
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DOI: 10.1016/j.jorganchem.2018.02.003
Abstract: Abstract The interdigitated and layered structures of the tetraalkylferrocenium salts [DEC][CB11H12], [DEC]2[B12F12], [DEC][BF4], [DEC][PF6], and [DEC][ClO3] were determined by single-crystal X-ray diffraction (DEC+ = 1,1′,3,3′-tetrakis(2-methyl-2-nonyl)ferrocenium(1+)). The structures of the salts of the two smaller anions were similar… read more here.
Keywords: dec; methyl nonyl; ferrocenium; clo3 ... See more keywords
A Charge-Transfer Salt Based on Ferrocene/Ferrocenium Pairs and Keggin-Type Polyoxometalates
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DOI: 10.3390/molecules23123150
Abstract: A new hybrid inorganic-organometallic salt has been obtained from the reaction of the Keggin-type silicotungstate anion with ferrocene in a water/methanol mixture as a result of the partial oxidation of ferrocene molecules to ferrocenium cations.… read more here.
Keywords: ferrocene; ferrocenium; salt; keggin type ... See more keywords
Ferrocenophanium Stability and Catalysis
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DOI: 10.3390/molecules28062729
Abstract: Ferrocenium catalysis is a vibrant research area, and an increasing number of ferrocenium-catalyzed processes have been reported in the recent years. However, the ferrocenium cation is not very stable in solution, which may potentially hamper… read more here.
Keywords: ferrocenophanium stability; ferrocenophanium; stability catalysis; stability ... See more keywords