Aerogel based on nanoporous aluminium ferrocenyl diphosphinate metal-organic framework
Sign Up to like & getrecommendations! Published in 2021 at "Inorganica Chimica Acta"
DOI: 10.1016/j.ica.2020.120240
Abstract: Abstract New porous coordination polymer (PCP) has been synthesized using ferrocene-based ligand bearing phosphinic groups (H2fcdHp = 1,1′-ferrocenediyl-bis(H-phosphinic acid)) and aluminum salt. Al-fcdHp was obtained according to a sol–gel approach followed by supercritical CO2 drying. The N2… read more here.
Keywords: ferrocenyl; aerogel based; nanoporous aluminium; aluminium ferrocenyl ... See more keywords
Bioactive 1,1′-unsymmetrical bi-functional ferrocenyl compounds using a novel solvent free one pot multicomponent reaction method
Sign Up to like & getrecommendations! Published in 2020 at "Journal of Organometallic Chemistry"
DOI: 10.1016/j.jorganchem.2019.121095
Abstract: Abstract A solvent free synthetic method using rice husk ash (RHA) as solid support has been designed for selective functionalization and preparation of novel 1,1′- unsymmetrically bi-functionalized ferrocenyl compounds. The selectively functionalized intermediate compound, Ferrocenyl-1-acetyl-1′-thiosemicarbazone,… read more here.
Keywords: ferrocenyl; unsymmetrical functional; ferrocenyl compounds; method ... See more keywords
Synthesis, structural and electrochemical characterization of novel 1,3-ketoureas bearing a ferrocenyl group
Sign Up to like & getrecommendations! Published in 2018 at "Polyhedron"
DOI: 10.1016/j.poly.2017.12.018
Abstract: Abstract Twenty-two novel 1,3-ketourea derivatives bearing ferrocene moiety were synthesized in good-to-excellent yields (up to 99%) via simple and efficient protocol. This solvent- and catalyst-free synthesis was achieved by additions of different ferrocene-containing Mannich bases… read more here.
Keywords: ferrocenyl; characterization novel; synthesis structural; electrochemical characterization ... See more keywords
The flexibility of periphery enhances the electrochemical reversibility of ferrocenyl-terminated polyphenylene dendrimers
Sign Up to like & getrecommendations! Published in 2021 at "Polymer"
DOI: 10.1016/j.polymer.2021.123929
Abstract: Abstract Four dendrimers of the first and second generations containing rigid polyphenylene interior and flexible ferrocenyl-terminated alkyl arms (CH2)m(C5H4)Fe(C5H5) (m = 6, 11) were synthesized by combining two types of “click” reactions: Diels-Alder and copper-catalyzed azide-alkyne cycloaddition… read more here.
Keywords: ferrocenyl; periphery enhances; flexibility periphery; ferrocenyl terminated ... See more keywords
Synthesis and Characterization of Ferrocenyl Chlorins, 1,1'-Ferrocene-Linked Chlorin Dimers, and their BODIPY Analogues.
Sign Up to like & getrecommendations! Published in 2017 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.6b03158
Abstract: We present the synthesis and characterization of meso-ferrocenyl-substituted hydroporphyrins (chlorins) and 1,1'-linked chlorin dimers. The dipyrromethane chlorin precursors were also transformed into Fc-substituted BODIPYs and 1,1'-ferrocenyl-linked BODIPY dimers. The chlorin dimers were studied by 1D… read more here.
Keywords: ferrocenyl; chlorin dimers; linked chlorin; chlorin ... See more keywords
Redox Isomeric Ferrocenyl Styrylruthenium Radical Cations with Diphenyl-Substituted β-Ketoenolato Ligands
Sign Up to like & getrecommendations! Published in 2019 at "Organometallics"
DOI: 10.1021/acs.organomet.9b00714
Abstract: We report on 18-valence-electron ferrocenyl vinylruthenium conjugates 4-Fc-C6H4-CH═CH-Ru(CO)Cl(PiPr3)2(PhR2acac) where PhR2acac denotes a diphenylacetylacetonato ligand with two 4-substituted (R = ... read more here.
Keywords: ferrocenyl; isomeric ferrocenyl; redox isomeric; radical cations ... See more keywords
Linker permethylation as a means to foster valence tautomerism and thwart dimerization in ferrocenyl-triarylmethylium cations.
Sign Up to like & getrecommendations! Published in 2023 at "Dalton transactions"
DOI: 10.1039/d3dt00857f
Abstract: Permethylation of the phenylene linker in a cationic ferrocenyl-phenylthioxanthylium dyad increases the amount of the diradical ferrocenium thioxanthyl radical valence tautomer and aids in supressing dimerization of the latter and of the one-electron reduced neutral… read more here.
Keywords: permethylation; dimerization; linker permethylation; ferrocenyl ... See more keywords