Ferroelastic-like transition and solvents affect the magnetism of a copper-organic radical one-dimensional coordination polymer.
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DOI: 10.1039/d2dt00135g
Abstract: The one-dimensional coordination polymers {[CuII(hfac)2]3(m-BNN)}n·nCH2Cl2 (1·CH2Cl2, P1̄) and {[CuII(hfac)2]3(m-BNN)}n (1', P2/n), hfac = hexafluoroacetylacetonate and m-BNN = meta-phenylene bis(nitronyl-nitroxide), were obtained from CH2Cl2 and CHCl3, respectively. 1·CH2Cl2 is transformed to 1 at 335 K. Their… read more here.
Keywords: ferroelastic like; like transition; dimensional coordination; one dimensional ... See more keywords