A ferromagnetic Ni(ii)–Cr(iii) single-chain magnet based on pentagonal bipyramidal building units
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DOI: 10.1039/c9qi01489f
Abstract: A Ni(II) complex harnessed in a pentagonal bipyramidal environment by a rigid N5-macrocyclic ligand (i.e. 1,3,10,12-tetramethyl-1,2,11,12-tetraaza[3](2,6)-pyridino[3](2,9)-1,10-phenanthrolinophane-2,10-diene) is shown to exhibit axial anisotropy with a ZFS D parameter in the order of −10 to −15 cm−1,… read more here.
Keywords: chain; ferromagnetic iii; iii single; pentagonal bipyramidal ... See more keywords