A Ferromagnetically Coupled, Bell-Shaped [Ni4Gd5] Cage.
Sign Up to like & getrecommendations! Published in 2019 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.9b00946
Abstract: Reaction between NiCl2·6H2O, 2-hydroxy-4-methyl-6-phenyl-pyridine-3-amidoxime (H2L), benzoic acid, and M(NO3)3·6H2O (M = Gd, Y) in MeCN under basic conditions yields the complexes [NiII4GdIII5(PhCOO)10(HL)4(HLzw)4(OH)2(NO3)2]Cl·13.6MeCN·H2O (1·13.6MeCN·H2O) and [NiII4YIII5(PhCOO)10(HL)4(HLzw)4(OH)2(NO3)1.5(H2O)0.5]0.5Cl(NO3)·3H2O (2·3H2O). Both clusters display similar structures, consisting of a bell-shaped… read more here.
Keywords: ni4gd5 cage; bell; shaped ni4gd5; ferromagnetically coupled ... See more keywords
A simple methodology for constructing ferromagnetically coupled Cr(iii) compounds.
Sign Up to like & getrecommendations! Published in 2018 at "Dalton transactions"
DOI: 10.1039/c8dt01963k
Abstract: A large family of chromium(iii) dimers has been synthesised and magneto-structurally characterised using a combination of carboxylate and diethanolamine type ligands. The compounds have the general formula [Cr2(R1-deaH)2(O2CR2)Cl2]Cl where R1 = Me and R2 =… read more here.
Keywords: methodology; methodology constructing; coupled iii; ferromagnetically coupled ... See more keywords
A ferromagnetically coupled pseudo-calixarene [Co16] wheel that self-assembles as a tubular network of capsules.
Sign Up to like & getrecommendations! Published in 2022 at "Dalton transactions"
DOI: 10.1039/d2dt02554j
Abstract: Reaction of Co(OAc)2·4H2O and Hsal in a basic MeCN solution affords the hexadecanuclear wheel [Co16(sal)16(OAc)16]·16MeCN (1·16MeCN) that displays ferromagnetic nearest neighbour exchange and has pseudo-calixarene character. Symmetry equivalent wheels self-assemble to form remarkable tubular networks… read more here.
Keywords: wheel; pseudo calixarene; co16; ferromagnetically coupled ... See more keywords