Probing Ferryl Reactivity in a Nonheme Iron Oxygenase Using an Expanded Genetic Code
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DOI: 10.1021/acscatal.4c02365
Abstract: The ability to introduce noncanonical amino acids as axial ligands in heme enzymes has provided a powerful experimental tool for studying the structure and reactivity of their FeIV=O (“ferryl”) intermediates. Here, we show that a… read more here.
Keywords: ferryl reactivity; reactivity nonheme; probing ferryl; nonheme iron ... See more keywords