Polyoxometalate-based heteronuclear complexes [Fe 2 M 2 (H 2 O) 2 (FeW 9 O 34 ) 2 ] n− (M=Mn II , Mn III , Ni II ) prepared by a pH-controllable degradation approach
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DOI: 10.1016/j.ica.2016.12.010
Abstract: Abstract Three new heteronuclear [FeW9O34]-based sandwich-type complexes [FeIII2MnII2(H2O)2(FeW9O34)2]12− (1), [FeIII2MnIII2(H2O)2(FeW9O34)2]10− (2) and [FeIII2NiII2(H2O)2(FeW9O34)2]12− (3) have been synthesized by an innovative method of pH-controllable degradation in aqueous solution, in which the [FeW12O40]5− precursor could be predominantly… read more here.
Keywords: polyoxometalate based; controllable degradation; heteronuclear complexes; h2o few9o34 ... See more keywords