Articles with "first coordination" as a keyword



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Effect of the ionic radius of stabilizing oxide cation on the local structure and transport properties of zirconia based solid solutions

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Published in 2021 at "Journal of Alloys and Compounds"

DOI: 10.1016/j.jallcom.2021.159396

Abstract: Abstract Features of the local structure of ZrO2-Yb2O3, ZrO2-Y2O3-Yb2O3 and ZrO2-Sc2O3-Yb2O3 single crystals have been studied using optical spectroscopy. The probability of oxygen vacancies to occupy the first coordination shells of the Sc3+, Yb3+ and… read more here.

Keywords: coordination shells; yb2o3; stabilizing oxide; solid solutions ... See more keywords
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The first coordination polymers with an [O]2[N]P(S)-Hg segment: a combined experimental, theoretical and database study.

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Published in 2019 at "Dalton transactions"

DOI: 10.1039/c9dt03546j

Abstract: The study of one-dimensional coordination polymers {Hg2Cl4L1}n (1), {HgBr2L1}n (2) and {Hg2Cl4L2}n (3) (L1 = (S)P(OC2H5)2NHC6H4NHP(S)(OC2H5)2 and L2 = (S)P(OC2H5)2NC4H8NP(S)(OC2H5)2) is the first such structural study of Hg(ii) coordination polymers with (O)2(N)PS-based ligands. The mercury… read more here.

Keywords: polymers segment; first coordination; study; coordination polymers ... See more keywords
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Syntheses and structural characterizations of the first coordination polymers assembled from the Ni(cyclam)2+ cation and the benzene-1,3,5-tricarboxylate linker

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Published in 2022 at "Acta Crystallographica Section E: Crystallographic Communications"

DOI: 10.1107/s2056989022009860

Abstract: The coordination polyhedra of the complex cations in the one-dimensional coordination polymers I and II represent tetragonally distorted NiN4O2 octahedra with the four N atoms of the azamacrocyclic cyclam ligand in the equatorial planes and… read more here.

Keywords: first coordination; characterizations first; coordination; structural characterizations ... See more keywords