First Example of Cationic Cyclopentadienyliron Based Chromene Complexes and Polymers: Synthesis, Characterization, and Biological Applications
Sign Up to like & getrecommendations! Published in 2019 at "Journal of Inorganic and Organometallic Polymers and Materials"
DOI: 10.1007/s10904-019-01295-w
Abstract: The present work encompasses development of a new class of active antimicrobial agents of the ɳ 6 -arene-ɳ 5 -cyclopentadienyliron (II) complexes and polymers to expand the existing family of antimicrobials. The design of the… read more here.
Keywords: complexes polymers; chromene; first example; cyclopentadienyliron ... See more keywords
Synthesis of multimeric pyrrolidine iminosugar inhibitors of human β-glucocerebrosidase and α-galactosidase A: First example of a multivalent enzyme activity enhancer for Fabry disease.
Sign Up to like & getrecommendations! Published in 2020 at "European journal of medicinal chemistry"
DOI: 10.1016/j.ejmech.2020.112173
Abstract: The synthesis of a chemical library of multimeric pyrrolidine-based iminosugars by incorporation of three pairs of epimeric pyrrolidine-azides into different alkyne scaffolds via CuAAC is presented. The new multimers were evaluated as inhibitors of two… read more here.
Keywords: enzyme activity; first example; fabry disease; multimeric pyrrolidine ... See more keywords
First example of peroxosolvate of iodine-containing organic molecule
Sign Up to like & getrecommendations! Published in 2021 at "Mendeleev Communications"
DOI: 10.1016/j.mencom.2021.04.023
Abstract: Six new bispidine-based bis-amides containing residues of haloacetic acids were synthesized and characterized by X-ray crystallography. The dissolution of iodine-containing compound in concentrated hydrogen peroxide afforded bispidine peroxosolvate, in which the peroxide molecules participated in… read more here.
Keywords: example peroxosolvate; iodine; first example; peroxosolvate iodine ... See more keywords
First Example of Protonation of Ruddlesden–Popper Sr2IrO4: A Route to Enhanced Water Oxidation Catalysts
Sign Up to like & getrecommendations! Published in 2020 at "Chemistry of Materials"
DOI: 10.1021/acs.chemmater.0c00432
Abstract: Water electrolysis is considered to be a promising way to store and convert excess renewable energies into hydrogen, which is of high value for many chemical transformation processes such as the Ha... read more here.
Keywords: ruddlesden popper; water; first example; popper sr2iro4 ... See more keywords
The first example of “turn-off” red fluorescence photoswitching for the representatives of nitrile-rich negative photochromes
Sign Up to like & getrecommendations! Published in 2020 at "New Journal of Chemistry"
DOI: 10.1039/d0nj00718h
Abstract: Representatives of negative photochromes containing a nitro-substituted 2-vinylphenolic fragment and a tricyanofuran (TCF) acceptor were synthesized. An efficient “turn-off” fluorescence photoswitching with full reversibility was shown for these compounds due to the negative photochromic transformation… read more here.
Keywords: nitrile rich; fluorescence; fluorescence photoswitching; first example ... See more keywords
First example of solid-state luminescent borasiloxane-based chiral helices assembled through N-B bonds.
Sign Up to like & getrecommendations! Published in 2021 at "Dalton transactions"
DOI: 10.1039/d1dt00114k
Abstract: The reaction between differently substituted borasiloxanes and 2,5-bis(3-pyridylethynyl)thiophene provided the first example of luminescent borasiloxane-based chiral helices held together by N-B bonds. The starting building blocks and the helices were fully characterized, and the nature… read more here.
Keywords: based chiral; first example; chiral helices; luminescent borasiloxane ... See more keywords
The First Example of Electron Phototransfer with the Participation of Two-Decker Lanthanide Phthalocyaninate
Sign Up to like & getrecommendations! Published in 2018 at "Protection of Metals and Physical Chemistry of Surfaces"
DOI: 10.1134/s2070205118020065
Abstract: The photochemical activity of the anionic form of two-decker ytterbium and lutetium pthalocyaninates (LnPc2, Ln = Yb, Lu) is observed in the process of electron transfer to 2-methyl-1,4-naphthoquinone (MNQ). Under illumination of solutions of LnPc2… read more here.
Keywords: electron phototransfer; first example; two decker; example electron ... See more keywords
First Example of Fluorinated Phenanthroline Diamides: Synthesis, Structural Study, and Complexation with Lanthanoids
Sign Up to like & getrecommendations! Published in 2022 at "Molecules"
DOI: 10.3390/molecules27154705
Abstract: An efficient approach to the synthesis of diamides of 4,7-difluoro-1,10-phenanthroline-2,9-dicarboxylic acid was elaborated. Direct nucleophilic substitution with 4,7-dichloro-1,10-phenanthroline precursors opened access to difluoro derivatives in high yield. As a result, four new fluorinated ligands were… read more here.
Keywords: first example; phenanthroline; spectroscopy; phenanthroline diamides ... See more keywords