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Published in 2018 at "Applied Surface Science"
DOI: 10.1016/j.apsusc.2017.11.035
Abstract: Abstract Ab-initio calculations based on density functional theory (DFT) have been performed to study systems where a first row transition metal atom is embedded in a rippled graphene due to the existence of an 8-order…
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Keywords:
system;
transition metal;
row transition;
rippled graphene ... See more keywords
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Published in 2020 at "Coordination Chemistry Reviews"
DOI: 10.1016/j.ccr.2020.213523
Abstract: This article reviews over the past 10 years the development of bifunctional homogeneous catalysts based on first row transition metals for asymmetric hydrogenation of various CC, CO and CN double bonds. Following the impressive performances…
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Keywords:
row transition;
catalysts based;
hydrogenation;
transition metals ... See more keywords
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Published in 2017 at "Inorganica Chimica Acta"
DOI: 10.1016/j.ica.2017.12.032
Abstract: Abstract Crystal structures of five first-row transition metal complexes of a recently-available bis-pyrazolylpyridine (bpp) ligand, 2,6-bis(3′,5′-diphenylpyrazolyl)pyridine (bdppp), prepared by reaction with transition metal chlorides, are reported. The ligand forms two types of structures, a 2:1…
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Keywords:
ligand bis;
bis diphenylpyrazolyl;
metal;
metal complexes ... See more keywords
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Published in 2020 at "Inorganica Chimica Acta"
DOI: 10.1016/j.ica.2020.119950
Abstract: Abstract The rich chemistry, low cost and availability offered by first-row transition metals have inspired many researchers to focus on the design, preparation and testing of a wide plethora of efficient catalytic systems for homogeneous…
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Keywords:
evolution;
row transition;
homogeneous light;
hydrogen evolution ... See more keywords
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Published in 2021 at "Optics and Laser Technology"
DOI: 10.1016/j.optlastec.2020.106570
Abstract: Abstract Electronic as well as nonlinear optical properties (first hyperpolarizabilities) of boron phosphide nanoclusters doped with first row transition metals (Sc–Zn) are explored using density functional theory (DFT) calculations. Four different doping sites (b64, b66,…
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Keywords:
boron phosphide;
first row;
transition metals;
nonlinear optical ... See more keywords
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Published in 2019 at "Polyhedron"
DOI: 10.1016/j.poly.2019.02.056
Abstract: Abstract Michael addition of 3-tert-butylpyrazole (1) or 3,5-dimethylpyrazole (2) to acrylamide afforded the pyrazolylpropanamide-type ligands 3-(3-tert-pyrazol-1-yl)propanamide (3, = tBuPPA) and 3-(3,5-dimethylpyrazol-1-yl)propanamide (4, = Me2PPA), respectively, in high isolated yields (3: 80%, 4: 76%). Reactions of 4 with selected first-row…
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Keywords:
transition metal;
three different;
coordination;
dimethylpyrazol propanamide ... See more keywords
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Published in 2023 at "Accounts of chemical research"
DOI: 10.1021/acs.accounts.2c00798
Abstract: ConspectusHomogeneous catalysis is at the forefront of global efforts to innovate the synthesis of fine chemicals and achieve carbon-neutrality in energy applications. For decades, the push toward sustainable catalysis has focused on the development of…
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Keywords:
first row;
pincer;
catalyst;
row metal ... See more keywords
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Published in 2020 at "Inorganic Chemistry"
DOI: 10.1021/acs.inorgchem.0c02294
Abstract: The formation of ternary hydrogen-rich hydrides involving the first-row transition metals TM = Fe and Co in high oxidation states is demonstrated from in situ synchrotron diffraction studies of reaction mixtures NaH–TM–H2 at p ≈…
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Keywords:
na3feh7 na3coh6;
row transition;
hydrogen rich;
pressure ... See more keywords
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Published in 2018 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.8b01207
Abstract: Three Wells-Dawson polyoxotungstates-based hybrid compounds of general formula [M(C3H7NO)6][{M(C3H7NO)5}2(μ-P2W18O62)]· nC3H7NO· n'H2O [with M = MnII (1), FeII (2), CoII (3) ; n = 2, 2, 3 and n' = 0, 0, 1, respectively] were synthesized…
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Keywords:
row transition;
octahedral first;
wells dawson;
series octahedral ... See more keywords
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Published in 2021 at "Journal of Physical Chemistry C"
DOI: 10.1021/acs.jpcc.0c10877
Abstract: The synthesis of single-atom catalysts (SACs) is one of the main challenges in heterogeneous catalysis and electrocatalysis since it requires substrates with high thermal/chemical stability on whic...
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Keywords:
single atom;
atom catalysts;
row transition;
interaction first ... See more keywords
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Published in 2021 at "ACS Catalysis"
DOI: 10.1021/acscatal.1c01077
Abstract: The stereoselective transformation of ketones to substituted olefins has become of great importance in organic synthesis. This Review helps to define the scope and limitations of the first-row tran...
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Keywords:
cross coupling;
coupling ketone;
ketone enolates;
grignard zinc ... See more keywords