Articles with "five coordinated" as a keyword



A Bioinspired Five‐Coordinated Single‐Atom Iron Nanozyme for Tumor Catalytic Therapy

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Published in 2022 at "Advanced Materials"

DOI: 10.1002/adma.202107088

Abstract: Single‐atom nanozymes (SAzymes) represent a new research frontier in the biomedical fields. The rational design and controllable synthesis of SAzymes with well‐defined electronic and geometric structures are essential for maximizing their enzyme‐like catalytic activity and… read more here.

Keywords: five coordinated; single atom; iron; tumor ... See more keywords

Nature of Five-Coordinated Al in γ-Al2O3 Revealed by Ultra-High-Field Solid-State NMR

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Published in 2022 at "ACS Central Science"

DOI: 10.1021/acscentsci.1c01497

Abstract: Five-coordinated Als (Al(V)) on the surface of aluminas play important roles when they are used as catalysts or catalyst supports. However, the comprehensive characterization and understanding of the intrinsic structural properties of the Al(V) remain… read more here.

Keywords: five coordinated; field solid; state nmr; solid state ... See more keywords

Slow magnetic relaxation in dinuclear Co(III)-Co(II) complexes containing a five-coordinated Co(II) centre with easy-axis anisotropy.

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Published in 2022 at "Dalton transactions"

DOI: 10.1039/d2dt00857b

Abstract: Two air-stable Co(III)-Co(II) mixed-valence complexes of molecular formulas [CoIICoIII(L)(DMAP)3(CH3COO)]·H2O·CH3OH (1) and [CoIICoIII(L)(4-Pyrrol)3 (CH3COO)]·0.5CH2Cl2 (2) (H4L = 1,3-bis-(5-methyl pyrazole-3-carboxamide) propane; DMAP = 4-dimethylaminopyridine; and 4-Pyrrol = 4-pyrrolidinopyridine) were synthesized and characterized by single-crystal X-ray crystallography, high-field… read more here.

Keywords: dinuclear iii; five coordinated; iii; easy axis ... See more keywords

Experimental determination of the magnetic anisotropy in five-coordinated Co(ii) field-induced single molecule magnets

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Published in 2025 at "Chemical Science"

DOI: 10.1039/d5sc03103f

Abstract: Magnetic anisotropy of the central metal atom is a crucial property of single molecule magnets (SMMs). Small structural changes can alter the magnetic properties, and accurate experimental methods to investigate magnetic anisotropy are therefore critical.… read more here.

Keywords: five coordinated; molecule magnets; anisotropy; magnetic anisotropy ... See more keywords

Spectroscopic Study of Five-Coordinated Thermal Treated Alumina Formation: FTIR and NMR Applying

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Published in 2023 at "International Journal of Molecular Sciences"

DOI: 10.3390/ijms24065151

Abstract: This work represents research into materials designed to improve the environment. The study was carried out on aluminum hydroxide xerogels and alumina catalysts obtained by the Controlled Double Jet Precipitation (CDJP) process at different pH… read more here.

Keywords: five coordinated; study five; spectroscopic study; coordinated thermal ... See more keywords