The flexibility of long chain substituents influences spin-crossover in isomorphous lipid bilayer crystals.
Sign Up to like & getrecommendations! Published in 2021 at "Chemical communications"
DOI: 10.1039/d1cc01073e
Abstract: [Fe(bpp)2][BF4]2 (bpp = 2,6-di{pyrazol-1-yl}pyridine) derivatives with a bent geometry of hexadec-1-ynyl or hexadecyl pyrazole substituents are isomorphous, and high-spin at room temperature. However, only the latter compound undergoes an abrupt, stepwise spin-transition on cooling. This… read more here.
Keywords: chain substituents; long chain; substituents influences; flexibility long ... See more keywords