High-pressure reversibility in a plastically flexible coordination polymer crystal
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DOI: 10.1038/s41467-021-24165-x
Abstract: Single crystals which exhibit mechanical flexibility are promising materials for advanced technological applications. Before such materials can be used, a detailed understanding of the mechanisms of bending is needed. Using single crystal X-ray diffraction and… read more here.
Keywords: plastically flexible; coordination polymer; flexible coordination; high pressure ... See more keywords
Emergence of electrical conductivity in a flexible coordination polymer by using chemical reduction.
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DOI: 10.1039/d0cc03062g
Abstract: A flexible coordination polymer with a naphthalenediimide core exhibited reversible desorption-adsorption of solvent molecules and an enhancement of electrical conductivity (∼10-7 S cm-1) upon chemical reduction using hydrazine. read more here.
Keywords: chemical reduction; electrical conductivity; coordination polymer; flexible coordination ... See more keywords
Flexible coordination of carbodiphosphorane-based pincer ligands in chromium(0) carbonyl complexes
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DOI: 10.1139/cjc-2020-0351
Abstract: A series of chromium(0) complexes was obtained by subsequent irradiation of [Cr(CO)6] in the presence of [(Ph2P-CH2-PPh2)CH]+. Depending on the reaction conditions and the duration of irradiation, ... read more here.
Keywords: carbodiphosphorane based; coordination carbodiphosphorane; ligands chromium; pincer ligands ... See more keywords