Solvent-Effected Coordination Variation of Flexible Ligands to Cu(II) for the Formation of 1D and 2D Secondary Building Units for Metal-Organic Frameworks.
Sign Up to like & getrecommendations! Published in 2021 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.1c00361
Abstract: Producing more than one structure from the same set of metal and ligand precursors will grant structural diversity in metal-organic framework (MOF) systems. One of the biggest obstacles of getting structural diversity for the late… read more here.
Keywords: coordination; secondary building; flexible ligands; building units ... See more keywords
Multivariant synthesis, crystal structures and properties of four nickel coordination polymers based on flexible ligands
Sign Up to like & getrecommendations! Published in 2018 at "CrystEngComm"
DOI: 10.1039/c8ce00837j
Abstract: Four new Ni(II) coordination polymers, namely, [Ni(HL)(bpe)(H2O)2]n·nH2O (1), [Ni2(L)(bpe)(μ3-OH)(H2O)]n·3nH2O (2), [Ni(L)(bpe)(H2O)]n·[Ni0.5(bpe)0.5(H2O)2]n·nH2O (3) and [Ni(HL)(bpe)(H2O)]n·3nH2O (4) based on flexible ligands 5-(3-carboxybenzyloxy)-isophthalic acid (H3L) and 1,2-bis(4-pyridyl)ethane (bpe) have been successfully synthesized under different conditions. Compounds 1 and… read more here.
Keywords: flexible ligands; bpe; bpe h2o; coordination polymers ... See more keywords
Dense π-stacking of flexible ligands fixed in interpenetrating Zn(ii) MOF exhibiting long-lasting phosphorescence and efficient carrier transport.
Sign Up to like & getrecommendations! Published in 2020 at "Dalton transactions"
DOI: 10.1039/d0dt01810d
Abstract: Three-fold interpenetrating Zn(ii) MOF with the dense π-stacking of flexible ligands exhibit long-lived phosphorescence emission up to 91 ms at room temperature. Photoelectric measurements show efficient electro-hole separation based on the long lifetime of triplet… read more here.
Keywords: stacking flexible; flexible ligands; phosphorescence; dense stacking ... See more keywords