Discriminatory Gate-Opening Effect in a Flexible Metal-Organic Framework for Inverse CO2 /C2 H2 Separation.
Sign Up to like & getrecommendations! Published in 2023 at "Small"
DOI: 10.1002/smll.202302975
Abstract: Considering the significant application of acetylene (C2 H2 ) in the manufacturing and petrochemical industries, the selective capture of impurity carbon dioxide (CO2 ) is a crucial task and an enduring challenge. Here, a flexible… read more here.
Keywords: organic framework; framework; metal organic; gate opening ... See more keywords
Free energy calculations for adsorption-induced deformation of flexible metal–organic frameworks
Sign Up to like & getrecommendations! Published in 2019 at "Current Opinion in Chemical Engineering"
DOI: 10.1016/j.coche.2019.01.001
Abstract: Flexible metal–organic frameworks (MOFs) are characterized by their responsiveness to guest adsorption, which is called ‘gate opening’ or ‘breathing’. Free energy calculations are tools for evaluating the stability of these systems, and are crucial for… read more here.
Keywords: adsorption; metal organic; flexible metal; free energy ... See more keywords
Low-temperature ultrasonic spray deposited aluminum doped zinc oxide film and its application in flexible Metal-Insulator-Semiconductor diodes
Sign Up to like & getrecommendations! Published in 2018 at "Thin Solid Films"
DOI: 10.1016/j.tsf.2017.11.006
Abstract: Abstract In this work, the fabrication and characterization of fully solution-processed flexible Metal-Insulator-Semiconductor (MIS) diodes are presented. The MIS structure was fabricated using aluminum doped zinc oxide and spin-on glass as semiconductor and insulator, respectively.… read more here.
Keywords: flexible metal; semiconductor; aluminum doped; insulator semiconductor ... See more keywords
Guest-Induced Switchable Breathing Behavior in a Flexible Metal-Organic Framework with Pronounced Negative Gas Pressure.
Sign Up to like & getrecommendations! Published in 2018 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.8b01408
Abstract: Flexible metal-organic frameworks (MOFs) have attracted great interest for their dynamically structural transformability in response to external stimuli. Herein, we report a switchable "breathing" or "gate-opening" behavior associated with the phase transformation between a narrow… read more here.
Keywords: flexible metal; pronounced negative; switchable breathing; metal organic ... See more keywords
Tuning the Atrazine Binding Sites in An Indium-Based Flexible Metal-Organic Framework.
Sign Up to like & getrecommendations! Published in 2020 at "ACS applied materials & interfaces"
DOI: 10.1021/acsami.0c13022
Abstract: Constructing flexible metal-organic frameworks (MOFs) with targeted properties is of high interest given their demonstrated potential as smart materials that undergo structural transformations in response to external stimuli. Herein, we report a flexible and interpenetrated… read more here.
Keywords: flexible metal; framework; indium based; metal organic ... See more keywords
Flexible Metal Electrodes by Femtosecond Laser-Activated Deposition for Human-Machine Interfaces.
Sign Up to like & getrecommendations! Published in 2022 at "ACS applied materials & interfaces"
DOI: 10.1021/acsami.2c00419
Abstract: Flexible metal electrodes are essential for flexible electronics, where the main challenge is to obtain mask-free patterned metals directly on substrates such as poly(dimethylsiloxane) (PDMS) at low cost. This work highlights a feasible strategy named… read more here.
Keywords: femtosecond laser; flexible metal; laser; deposition ... See more keywords
A Flexible Metal-Organic Framework with 4-Connected Zr6 Nodes.
Sign Up to like & getrecommendations! Published in 2018 at "Journal of the American Chemical Society"
DOI: 10.1021/jacs.8b06789
Abstract: Zr-based metal-organic frameworks (MOFs) have been known for their excellent stability; however, due to the high connectivity of the Zr6 nodes, it is challenging to introduce flexibility into Zr-MOFs. Here we present a flexible Zr-MOF… read more here.
Keywords: flexible metal; metal organic; zr6 nodes; organic framework ... See more keywords
Desolvation process in the flexible metal–organic framework [Cu(Me-4py-trz-ia)], adsorption of dihydrogen and related structure responses
Sign Up to like & getrecommendations! Published in 2019 at "CrystEngComm"
DOI: 10.1039/c9ce00992b
Abstract: Structural changes and the unusual H2 adsorption behaviour of a Cu2+-based MOF were studied by X-ray diffraction in combination with DFT modelling and by inelastic neutron scattering. read more here.
Keywords: desolvation process; flexible metal; adsorption; process flexible ... See more keywords
Isotope-selective pore opening in a flexible metal-organic framework
Sign Up to like & getrecommendations! Published in 2022 at "Science Advances"
DOI: 10.1126/sciadv.abn7035
Abstract: Flexible metal-organic frameworks that show reversible guest-induced phase transitions between closed and open pore phases have enormous potential for highly selective, energy-efficient gas separations. Here, we present the gate-opening process of DUT-8(Ni) that selectively responds… read more here.
Keywords: flexible metal; metal organic; gate opening; isotope selective ... See more keywords