FLP-CO2 adducts: convenient sources of frustrated Lewis pairs for stoichiometric and catalytic chemistry.
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DOI: 10.1039/d5dt00942a
Abstract: The compounds [tBu3PCO2B(C6F5)3] 1 and [TMPH][C5H6Me4NCO2B(C6F5)3] 7 are easily handled synthons releasing CO2 on warming generating the corresponding FLPs which can activate H2, disulfides, alkynes, silanes and phenols. Compound 7 was also shown to be… read more here.
Keywords: sources frustrated; chemistry; adducts convenient; flp co2 ... See more keywords