High magnetization reversal barriers in luminescent dysprosium octahedral and pentagonal bipyramidal single-molecule magnets based on fluorinated alkoxide ligands.
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DOI: 10.1039/d1dt01319j
Abstract: We report the synthesis and structures of three luminescent dysprosium(iii) complexes based on fluorinated alkoxide ligands of formulas [Dy(L1)2(THF)4][BPh4]·0.5THF (1), [Dy(L2)2(THF)5][BPh4]·2.5THF (2) and [Dy(L3)2(THF)5][BPh4]·2THF (3) (L1 = (CF3)3CO-, L2 = C6F5C6F4O-, L3 = C6F5C(CH3)O-). Despite… read more here.
Keywords: fluorinated alkoxide; single molecule; alkoxide ligands; based fluorinated ... See more keywords
Luminescent Er3+ based single molecule magnets with fluorinated alkoxide or aryloxide ligands.
Sign Up to like & getrecommendations! Published in 2024 at "Dalton transactions"
DOI: 10.1039/d3dt04375d
Abstract: We report the synthesis, structures, and magnetic and luminescence properties of a series of new mono- and dinuclear Er3+ complexes derived from sterically demanding aryloxide and fluorinated alkoxide ligands: [4-tBu-2,6-(Ph2CH)2C6H2O]3Er(THF) (1), [(C6F5)3CO]3Er(Me3SiOH) (2), [(C6F5)3CO]3Er[(Me3Si)2NH] (3),… read more here.
Keywords: fluorinated alkoxide; 3co 3er; molecule magnets; geometry ... See more keywords