Synthesis of Fluorinated Dialkyl Carbonates from Carbon Dioxide as a Carbonyl Source.
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DOI: 10.1002/cssc.202000090
Abstract: Fluorinated dialkyl carbonates, which serve as environmentally benign phosgene substitutes, were successfully produced from carbon dioxide either directly or indirectly. Nucleophilic addition of 2,2,2-trifluoroethanol to carbon dioxide and subsequent reaction with 2,2,2-trifluoroethyltriflate ( E OTf… read more here.
Keywords: dioxide carbonyl; fluorinated dialkyl; dialkyl carbonates; carbon dioxide ... See more keywords