α-Fluorination of Nitrobenzenes and Nitropyridines via Vicarious Nucleophilic Substitution of Hydrogen
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DOI: 10.1055/s-0039-1690862
Abstract: A highly selective C–H functionalization of nitrobenzenes and nitropyridines is reported using tandem vicarious nucleophilic substitution (VNS) chemistry with electrophilic fluorination using Selectfluor®. The process generates tertiary benzylic fluorides in good yield under simple, mild… read more here.
Keywords: fluorination nitrobenzenes; nucleophilic substitution; vicarious nucleophilic; nitrobenzenes nitropyridines ... See more keywords