Nucleophilic (Radio)Fluorination of Redox-Active Esters via Radical-Polar Crossover Enabled by Photoredox Catalysis.
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DOI: 10.1021/jacs.0c03125
Abstract: We report a redox-neutral method for nucleophilic fluorination of N-hydroxyphthalimide esters using an Ir photocatalyst under visible light irradiation. The method provides access to a broad range of aliphatic fluorides, including primary, secondary, and tertiary… read more here.
Keywords: fluorination redox; active esters; nucleophilic radio; fluorination ... See more keywords