Articles with "fluorine shifts" as a keyword



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Fluorine shifts from sulfur in dimethylaminodifluorosulfane complexes of cyclopentadienyl metal carbonyls of chromium, molybdenum, and tungsten

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Published in 2019 at "Polyhedron"

DOI: 10.1016/j.poly.2019.02.025

Abstract: Abstract Previous theoretical studies predict metal SF3 complexes to be disfavored relative to shift of a fluorine atom from the SF3 ligand to the metal atom to give complexes with separate SF2 and fluorine ligands.… read more here.

Keywords: metal; cpm; chromium molybdenum; molybdenum tungsten ... See more keywords