The Fluoro-Pauson-Khand Reaction in the Synthesis of Enantioenriched Nitrogenated Bicycles Bearing a Quaternary C-F Stereogenic Center.
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DOI: 10.1021/acs.orglett.9b02557
Abstract: A variety of enantioenriched fluorinated 6H-cyclopenta[c]pyridin-6-one bicycles, a scaffold present in several classes of monoterpenic alkaloids with varied biological activity, were synthesized in just five steps from simple aldehyde starting materials. The synthesis presented wide… read more here.
Keywords: reaction synthesis; synthesis enantioenriched; fluoro pauson; pauson khand ... See more keywords