Fluoro Silane Activation by Pd/Ni→Si‒F→Lewis Acid Interaction: an Entry to Catalytic Sila-Negishi Coupling.
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DOI: 10.1021/jacs.0c04690
Abstract: A new mode of bond activation involving M->Z interactions is disclosed. Coordination to transition metals as sigma-acceptor ligands was found to enable the activation of fluoro silanes, opening the way to the first transition met-al-catalyzed… read more here.
Keywords: fluoro silane; sila negishi; lewis acid; activation ... See more keywords