Mechanism-Dependent Selectivity: Fluorocyclization of Unsaturated Carboxylic Acids or Alcohols by Hypervalent Iodine
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DOI: 10.3389/fchem.2022.897828
Abstract: To understand the unprecedented difference between 6-endo and 5-exo selectivity in hypervalent iodine (III) promoted fluorocyclization of unsaturated carboxylic acids or alcohols by difluoroiodotoluene, density functional theory (DFT) studies have been performed to systematically compare… read more here.
Keywords: fluorocyclization; hypervalent iodine; mechanism dependent; mechanism ... See more keywords