Hydrogen bonding and fluorous weak interactions in the non-isomorphous {4,4'-bis[(2,2,3,3-tetrafluoropropoxy)methyl]-2,2'-bipyridine-κ2N,N'}dibromidopalladium and -platinum complexes.
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DOI: 10.1107/s2053229618005715
Abstract: The polyfluorinated title compounds, [MBr2(C18H16F8N2O2)] or [4,4'-(HCF2CF2CH2OCH2)2-2,2'-bpy]MBr2, (1) (M = Pd and bpy is bipyridine) and (2) (M = Pt), have -CH(α)2OCH(β)2CF2CF2H side chains with methylene H-atom donors at the α and β sites, and… read more here.
Keywords: fluorous weak; atom donors; weak interactions; bipyridine ... See more keywords