A five-fold interpenetrated metal-organic framework showing a large variation in thermal expansion behaviour owing to dramatic structural transformation upon dehydration-rehydration.
Sign Up to like & getrecommendations! Published in 2017 at "Chemical communications"
DOI: 10.1039/c6cc07995d
Abstract: A five-fold interpenetrated metal organic framework (MOF) has been shown to exhibit anomalous thermal expansion due to the combined effect of hinge-like motion and sliding of individual diamondoid networks. Upon dehydration, the MOF undergoes dramatic… read more here.
Keywords: interpenetrated metal; expansion; metal organic; five fold ... See more keywords
A new two-fold interpenetrated Cd(II)-based metal-organic framework as a fluorescent probe for nitro-aromatic compounds
Sign Up to like & getrecommendations! Published in 2020 at "Journal of Coordination Chemistry"
DOI: 10.1080/00958972.2020.1830975
Abstract: Abstract Luminescent metal-organic frameworks (MOFs) have been extensively investigated as sensors for detection of various compounds. In this work, 5,5',5''-((benzene-1,3,5-tricarbonyl)tris(azanediyl))triisophthalic acid (H6L) and 1,3,5-tri(1H-imidazol-1-yl)benzene (tib) were reacted with Cd(NO3)2ยท4H2O under solvothermal conditions to generate a… read more here.
Keywords: fluorescent probe; aromatic compounds; nitro aromatic; metal organic ... See more keywords