Forging O–O Bonds
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DOI: 10.1016/j.joule.2021.07.013
Abstract: The O–O bond-forming step in the oxidation of water to dioxygen is the key to how nature converts solar energy into renewable fuel, yet remains not fully understood. A recent report in Nature Chemistry from… read more here.
Keywords: forging bonds; chemistry;
Forging C–C Bonds with Hindered Nucleophiles and Carbonyl Electrophiles: Reactivity and Selectivity of Allylic Tin Reagents/n-BuLi
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DOI: 10.1021/acs.organomet.7b00765
Abstract: Under activation with n-BuLi, trialkylstannanes containing crotyl-, geranyl-, and phenyldienylmethyl appendages were reacted with efficiency and selectivity to various ketone and enone electrophiles with low reactivity. The straightforward process gives access to tertiary alcohols that… read more here.
Keywords: bonds hindered; forging bonds; nucleophiles carbonyl; reactivity ... See more keywords
Bodipy-Based Metal-Organic Frameworks Transformed in Solid States from 1D Chains to 2D Layer Structures as Efficient Visible Light Heterogeneous Photocatalysts for Forging C-B and C-C Bonds.
Sign Up to like & getrecommendations! Published in 2023 at "Journal of the American Chemical Society"
DOI: 10.1021/jacs.2c11647
Abstract: Boron dipyrromethene (also known as bodipy), as a class of versatile and robust fluorophores and a structural analogue of porphyrins, has received a great deal of interests in the field of light-harvesting and energy-transfer processes.… read more here.
Keywords: bodipy based; photocatalysts forging; organic frameworks; metal organic ... See more keywords