Copper-Catalyzed Formal Dehydration Polymerization of Propargylic Alcohols via Cumulene Intermediates.
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DOI: 10.1021/jacs.2c00599
Abstract: Here we report a copper-catalyzed formal dehydration polymerization of propargylic alcohols. Copper catalysis allows for efficient in situ generation of [n]cumulenes (n = 3, 5) by a soft deprotonation/β-elimination pathway and subsequent polymerization via organocopper… read more here.
Keywords: copper catalyzed; polymerization propargylic; dehydration polymerization; polymerization ... See more keywords