Iridium-Catalyzed Hydroiodination and Formal Hydroamination of Olefins with N-Iodo Reagents and Molecular Hydrogen: An Umpolung Strategy.
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DOI: 10.1021/acs.orglett.2c00392
Abstract: We herein report a convenient method to convert olefins to organic iodides and amines using an Ir/ZhaoPhos catalyst, molecular hydrogen, and an electrophilic iodine(I) reagent. High yields and regioselectivities were obtained under mild conditions. In… read more here.
Keywords: hydrogen; iridium catalyzed; hydroiodination formal; molecular hydrogen ... See more keywords