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Published in 2022 at "Chemical Science"
DOI: 10.1039/d2sc02496a
Abstract: We report a diversification strategy that enables the direct substituent exchange of tertiary phosphines. Alkylated phosphonium salts, prepared by standard alkylation of phosphines, are selectively dearylated in a nickel-catalysed process to access alkylphosphine products via…
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Keywords:
nickel catalysed;
substitution phosphorus;
diversification;
formal substitution ... See more keywords