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Published in 2020 at "Organic letters"
DOI: 10.1021/acs.orglett.0c01857
Abstract: A number of nitrile-containing chiral molecules were synthesized via asymmetric nucleophilic addition of formaldehyde N,N-dialkylhydrazone as the nitrile equivalent. Chiral N,N'-dioxide/metal salt complexes enabled the asymmetric addition reactions to both isatin-derived imines and α,β-unsaturated ketones,…
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Keywords:
formaldehyde dialkylhydrazone;
addition;
asymmetric addition;
addition reactions ... See more keywords