Monoclinic Scheelite Bismuth Vanadate Derived Bismuthene Nanosheets with Rapid Kinetics for Electrochemically Reducing Carbon Dioxide to Formate
Sign Up to like & getrecommendations! Published in 2020 at "Advanced Functional Materials"
DOI: 10.1002/adfm.202006704
Abstract: Electrochemical reduction of CO2 to high‐value chemical feedstocks, such as formate, is one of the most promising ways to alleviate the greenhouse effect. Unfortunately, the exploration of electrocatalysts with high activity and selectivity over a… read more here.
Keywords: formate; bismuthene nanosheets; bismuth vanadate; vanadate derived ... See more keywords
Selective Ethylene Glycol Oxidation to Formate on Nickel Selenide with Simultaneous Evolution of Hydrogen
Sign Up to like & getrecommendations! Published in 2023 at "Advanced Science"
DOI: 10.1002/advs.202300841
Abstract: There is an urgent need for cost‐effective strategies to produce hydrogen from renewable net‐zero carbon sources using renewable energies. In this context, the electrochemical hydrogen evolution reaction can be boosted by replacing the oxygen evolution… read more here.
Keywords: oxidation; reaction; formate; formate nickel ... See more keywords
Sodium formate redirects carbon flux and enhances heterologous mevalonate production in Methylobacterium extorquens AM1
Sign Up to like & getrecommendations! Published in 2022 at "Biotechnology Journal"
DOI: 10.1002/biot.202200402
Abstract: Methylobacterium extorquens AM1 (AM1), a model strain of methylotrophic cell factories (MeCFs) could be used to produce fine chemicals from methanol. Synthesis of heterologous products usually needs reducing cofactors, but AM1 growing on methanol lack… read more here.
Keywords: methylobacterium extorquens; formate; extorquens am1; sodium formate ... See more keywords
Single Iridium Pincer Complex for Roundtrip Electrochemical Conversion between Carbon Dioxide and Formate
Sign Up to like & getrecommendations! Published in 2019 at "ChemCatChem"
DOI: 10.1002/cctc.201900083
Abstract: An iridium (III) complex based on a PONOP pincer ligand (PONOP=2,6‐bis(di‐tert‐butylphosphinito)pyridine) is a versatile catalyst for both electro‐reduction of CO2 to formate and formate electro‐oxidation to CO2. The electro‐reduction of CO2 in acetonitrile is very… read more here.
Keywords: pincer; iridium; conversion; co2 ... See more keywords
Release of Formic Acid from Copper Formate: Hydride, Proton‐Coupled Electron and Hydrogen Atom Transfer All Play their Role
Sign Up to like & getrecommendations! Published in 2019 at "Chemphyschem"
DOI: 10.1002/cphc.201900095
Abstract: Abstract Although the mechanism for the transformation of carbon dioxide to formate with copper hydride is well understood, it is not clear how formic acid is ultimately released. Herein, we show how formic acid is… read more here.
Keywords: hydrogen atom; copper; formic acid; transfer ... See more keywords
Simultaneous anodic and cathodic formate production in a paired electrolyzer by CO2 reduction and glycerol oxidation.
Sign Up to like & getrecommendations! Published in 2023 at "ChemSusChem"
DOI: 10.1002/cssc.202202349
Abstract: Electrochemical CO2 conversion is a key technology to promote the production of carbon-containing molecules, alongside reducing CO2 emissions leading to a closed carbon cycle economy. Over the past decade, the interest to develop selective and… read more here.
Keywords: paired electrolyzer; formate; co2 reduction; production ... See more keywords
Formate and potassium ions affect Escherichia coli proton ATPase activity at low pH during mixed carbon fermentation
Sign Up to like & getrecommendations! Published in 2019 at "IUBMB Life"
DOI: 10.1002/iub.2219
Abstract: Escherichia coli is able to ferment not only single but also mixtures of carbon sources. The formate metabolism and effect of formate on various enzymes have been extensively studied during sole glucose but not mixed… read more here.
Keywords: atpase; potassium ions; formate; atpase activity ... See more keywords
Distinguishing functional from structural roles of conserved pore residues during formate translocation by the FocA anion channel
Sign Up to like & getrecommendations! Published in 2022 at "MicrobiologyOpen"
DOI: 10.1002/mbo3.1312
Abstract: The formate‐specific anion channel FocA of Escherichia coli belongs to the superfamily of homopentameric formate‐nitrite transporters (FNT). Minimally nine amino acid residues are conserved in the formate translocation pore of each protomer of the pentamer,… read more here.
Keywords: anion channel; translocation; formate; functional structural ... See more keywords
Nanoporous Intermetallic SnTe Enables Efficient Electrochemical CO2 Reduction into Formate via Promoting the Fracture of Metal-Oxygen Bonding.
Sign Up to like & getrecommendations! Published in 2022 at "Small"
DOI: 10.1002/smll.202107968
Abstract: Electrochemical reduction of CO2 into formate product is considered the most practical significance link in the carbon cycle. Developing cheap and efficient electrocatalysts with high selectivity for formate on a wide operated potential window is… read more here.
Keywords: reduction; formate; intermetallic snte; electrochemical co2 ... See more keywords
Selective CO2 Electroreduction to Formate on Polypyrrole-Modified Oxygen Vacancy-Rich Bi2 O3 Nanosheet Precatalysts by Local Microenvironment Modulation.
Sign Up to like & getrecommendations! Published in 2023 at "Small"
DOI: 10.1002/smll.202300001
Abstract: Challenges remain in the development of highly efficient catalysts for selective electrochemical transformation of carbon dioxide (CO2 ) to high-valued hydrocarbons. In this study, oxygen vacancy-rich Bi2 O3 nanosheets coated with polypyrrole (Bi2 O3 @PPy… read more here.
Keywords: oxygen vacancy; microenvironment; bi2; formate ... See more keywords
Quantification of Formate and Oxygen Coverages on Cu Under Industrial Methanol Synthesis Conditions
Sign Up to like & getrecommendations! Published in 2020 at "Catalysis Letters"
DOI: 10.1007/s10562-020-03162-7
Abstract: Abstract A method for quantifying the surface coverage of adsorbate species for reactions at high pressure and high temperature is presented. Methanol was synthesized from CO 2 /CO/H 2 (3/29/68) at 523 K and 50 bar on… read more here.
Keywords: oxygen; surface; methanol synthesis; formate ... See more keywords