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   Articles with "formate" as a keyword



In vivo evidence for glycyl radical insertion into a catalytically inactive variant of pyruvate formate‐lyase

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recommendations! Published in 2025 at "Febs Letters"

DOI: 10.1002/1873-3468.70075

Abstract: The dimeric glycyl radical enzyme pyruvate formate‐lyase (PflB; formate acetyltransferase 1) cleaves pyruvate with hypothetical half‐site reactivity to formate and acetyl‐CoA. The radical introduced onto residue G734 of PflB is transiently transferred to C419 of… read more here.

Keywords: formate lyase; variant; formate; glycyl radical ... See more keywords

Monoclinic Scheelite Bismuth Vanadate Derived Bismuthene Nanosheets with Rapid Kinetics for Electrochemically Reducing Carbon Dioxide to Formate

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recommendations! Published in 2020 at "Advanced Functional Materials"

DOI: 10.1002/adfm.202006704

Abstract: Electrochemical reduction of CO2 to high‐value chemical feedstocks, such as formate, is one of the most promising ways to alleviate the greenhouse effect. Unfortunately, the exploration of electrocatalysts with high activity and selectivity over a… read more here.

Keywords: formate; bismuthene nanosheets; bismuth vanadate; vanadate derived ... See more keywords

Fibrous Pb(II)‐Based Coordination Polymer Operable as a Photocatalyst and Electrocatalyst for High‐Rate, Selective CO2‐to‐Formate Conversion

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recommendations! Published in 2024 at "Advanced Functional Materials"

DOI: 10.1002/adfm.202417223

Abstract: A nonporous [Pb(tadt)]n (tadt = 1,3,4‐thiadiazole‐2,5‐dithiolate) coordination polymer, KGF‐9, with a 2D infinite (−Pb−S−)n structure has been previously reported as a precious‐metal‐free photocatalyst for selective CO2‐to‐formate conversion under visible light. In the present work, a… read more here.

Keywords: co2 formate; formate; coordination polymer; formate conversion ... See more keywords

Selective Ethylene Glycol Oxidation to Formate on Nickel Selenide with Simultaneous Evolution of Hydrogen

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recommendations! Published in 2023 at "Advanced Science"

DOI: 10.1002/advs.202300841

Abstract: There is an urgent need for cost‐effective strategies to produce hydrogen from renewable net‐zero carbon sources using renewable energies. In this context, the electrochemical hydrogen evolution reaction can be boosted by replacing the oxygen evolution… read more here.

Keywords: oxidation; reaction; formate; formate nickel ... See more keywords

Oxygen‐Pinned Ag1In Single‐Atom Alloy for Efficient Electroreduction CO2 to Formate

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recommendations! Published in 2024 at "Advanced Energy Materials"

DOI: 10.1002/aenm.202400813

Abstract: Catalytic conversion of CO2 to valuable formate provides a pathway to carbon neutrality. Indium (In), as a promising catalyst, exhibits high selectivity toward formate due to its suitable bonding ability of *OCHO intermediates. However, it… read more here.

Keywords: co2; formate; oxygen pinned; single atom ... See more keywords

Concentrated formate produced through co‐electrolysis of CO2 and methanol in a zero‐gap electrolyzer

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recommendations! Published in 2024 at "AIChE Journal"

DOI: 10.1002/aic.18382

Abstract: Recent progresses have highlighted the enormous potentials of renewable electricities driven carbon dioxide (CO2) electrolysis in achieving carbon neutrality. However, its further industrial application is limited by low liquid product concentrations, which requires energy‐intensive downstream… read more here.

Keywords: zero gap; co2; concentrated formate; formate ... See more keywords

Sodium formate redirects carbon flux and enhances heterologous mevalonate production in Methylobacterium extorquens AM1

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recommendations! Published in 2022 at "Biotechnology Journal"

DOI: 10.1002/biot.202200402

Abstract: Methylobacterium extorquens AM1 (AM1), a model strain of methylotrophic cell factories (MeCFs) could be used to produce fine chemicals from methanol. Synthesis of heterologous products usually needs reducing cofactors, but AM1 growing on methanol lack… read more here.

Keywords: methylobacterium extorquens; formate; extorquens am1; sodium formate ... See more keywords

Single Iridium Pincer Complex for Roundtrip Electrochemical Conversion between Carbon Dioxide and Formate

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recommendations! Published in 2019 at "ChemCatChem"

DOI: 10.1002/cctc.201900083

Abstract: An iridium (III) complex based on a PONOP pincer ligand (PONOP=2,6‐bis(di‐tert‐butylphosphinito)pyridine) is a versatile catalyst for both electro‐reduction of CO2 to formate and formate electro‐oxidation to CO2. The electro‐reduction of CO2 in acetonitrile is very… read more here.

Keywords: pincer; iridium; conversion; co2 ... See more keywords

Formate Dehydrogenase: Recent Developments for NADH and NADPH Recycling in Biocatalysis

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recommendations! Published in 2024 at "ChemCatChem"

DOI: 10.1002/cctc.202401021

Abstract: Formate dehydrogenases (FDHs) catalyze the oxidation of formate to CO2 while reducing NAD(P)+ to NAD(P)H and are classified into two main classes: metal‐dependent (Mo‐ or W‐containing) and metal‐independent FDHs. The latter are oxygen‐tolerant and relevant… read more here.

Keywords: dehydrogenase recent; recent developments; formate; biocatalysis ... See more keywords

Release of Formic Acid from Copper Formate: Hydride, Proton‐Coupled Electron and Hydrogen Atom Transfer All Play their Role

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recommendations! Published in 2019 at "Chemphyschem"

DOI: 10.1002/cphc.201900095

Abstract: Abstract Although the mechanism for the transformation of carbon dioxide to formate with copper hydride is well understood, it is not clear how formic acid is ultimately released. Herein, we show how formic acid is… read more here.

Keywords: hydrogen atom; copper; formic acid; transfer ... See more keywords

Simultaneous anodic and cathodic formate production in a paired electrolyzer by CO2 reduction and glycerol oxidation.

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recommendations! Published in 2023 at "ChemSusChem"

DOI: 10.1002/cssc.202202349

Abstract: Electrochemical CO2 conversion is a key technology to promote the production of carbon-containing molecules, alongside reducing CO2 emissions leading to a closed carbon cycle economy. Over the past decade, the interest to develop selective and… read more here.

Keywords: paired electrolyzer; formate; co2 reduction; production ... See more keywords