Stepwise methane to methanol conversion: Effect of copper loading on the formation of active species in copper-exchanged mordenite
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DOI: 10.1016/j.cattod.2020.11.027
Abstract: Abstract This work investigates the influences of Cu content, Si/Al ratio, and sample preparation method on the active Cu species in mordenite (MOR). The Cu/MOR prepared by multiple Cu-exchange procedures showed an optimum Cu/Al ratio… read more here.
Keywords: active species; stepwise methane; copper; formation ... See more keywords
Mechanism of formation of active catalytic species in nickel-catalysed asymmetric hydrogenation
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DOI: 10.71267/mencom.7818
Abstract: Initial stages of two representative Ni-catalysed asymmetric hydrogenations were investigated computationally featuring the formation of the active catalytic species [R,R-BenzP*NiH]+ from R,R-BenzP*Ni(OAc)2 and [S,S-Ph-BPENiH]+ from S,S-Ph-BPENi(OAc)2. Among several computed pathways the most feasible is dissociation… read more here.
Keywords: sup; formation active; active catalytic; sub ... See more keywords