Csp3–N bond formation in aminothiophenes by 1,1-dibromo isocyanide: the unexpected 1,5-binucleophilicity of substrates
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DOI: 10.1007/s13738-017-1195-9
Abstract: The N-cyclohexylcarbonimidoyl dibromide in situ, generated by cyclohexylisocyanide and bromine in reaction with several deactivated 5-acetyl-4-amino-2-methylsulfanyl-3-carbonitrile, appears as a cyclohexyl transformer to the substrate via Csp3–N bond formation without using any base or catalyst at… read more here.
Keywords: formation aminothiophenes; bond formation; reaction; csp3 bond ... See more keywords