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Formation of an α-Diimine from Isocyanide Coupling Using Thorium(IV) and Uranium(IV) Phosphido–Methyl Complexes

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Published in 2019 at "Organometallics"

DOI: 10.1021/acs.organomet.9b00043

Abstract: To probe the reactivity of two potential sites at tetravalent thorium and uranium metal centers, we examined the monophosphido methyl complexes, (C5Me5)2An(CH3)[P(SiMe3)(Mes)], An = Th, U; Mes = 2,... read more here.

Keywords: isocyanide coupling; formation diimine; diimine isocyanide; thorium uranium ... See more keywords