Formation of exceptional monomeric YPhos–PdCl2 complexes with high activities in coupling reactions
Sign Up to like & getrecommendations! Published in 2022 at "Chemical Science"
DOI: 10.1039/d2sc04523k
Abstract: The use of well-defined palladium(ii) complexes as precatalysts for C–X cross-coupling reactions has improved the use of palladium catalysts in organic synthesis including large-scale processes. Whereas sophisticated Pd(ii) precursors have been developed in the past… read more here.
Keywords: coupling reactions; formation exceptional; pdcl2 complexes; yphos pdcl2 ... See more keywords
Spontaneous Formation of Exceptional Points at the Onset of Magnetism.
Sign Up to like & getrecommendations! Published in 2022 at "Physical review letters"
DOI: 10.1103/physrevlett.130.186403
Abstract: We reveal how symmetry-protected nodal points in topological semimetals may be promoted to pairs of generically stable exceptional points (EPs) by symmetry-breaking fluctuations at the onset of long-range order. This intriguing interplay between non-Hermitian (NH)… read more here.
Keywords: exceptional points; formation exceptional; spontaneous formation; onset magnetism ... See more keywords